Anne Hathaway joins her husband Adam Shulman at the Valentino show for Paris Fashion Week

Anne Hathaway enjoyed a very rare reunion with husband Adam Shulman on Wednesday when they attended the Valentino Haute Couture show during Paris Fashion Week.

The 40-year-old Oscar winner – who dazzled alongside Rosie Huntington-Whiteley at the A-list show – rocked a stunning leopard print mini dress from the luxury fashion house.

The extremely private couple rarely attend events together, but Shulman, 41, looked dapper in a long gray coat as he accompanied his superstar wife.

Special: Anne Hathaway, 40, enjoyed a rare reunion with her handsome husband Adam Shulman, 41, on Wednesday as they attended the Valentino Haute Couture show during Paris Fashion Week

Resplendent in a dazzling leopard print, Anne turned heads in a mini dress and sexy leggings.

The Devil Wears Prada star exuded chic appeal in her leopard print shoes and even carried a matching clutch.

Exquisite jewelry adorned her hands and ears, while her radiant face shone with a soft, flawless glow.

Adam – who is an actor turned jewelery designer – pulled off a dainty look with his silver mane of hair.

Sporting some winter scrubs, the New York native paired a stylish sweater with black trousers and formal shoes.

Stunning: The Oscar winner rocked a stunning leopard print mini dress from the luxury fashion house, while Shulman looked dapper in a long gray coat

Stunning: The Oscar winner rocked a stunning leopard print mini dress from the luxury fashion house, while Shulman looked dapper in a long gray coat

Debonair pair: The Devil Wears Prada star exuded chic appeal in her leopard print shoes and even carried a matching clutch.  Adam – an actor turned jewelery designer – pulled off a great look with his silver mane

Debonair pair: The Devil Wears Prada star exuded chic appeal in her leopard print shoes and even carried a matching clutch. Adam – an actor turned jewelery designer – pulled off a great look with his silver mane

Cute: Hathaway has been married to Shulman since 2012 and the couple share two sons: Jonathan, six, and Jack, three

Cute: Hathaway has been married to Shulman since 2012 and the couple share two sons: Jonathan, six, and Jack, three

Hathaway has been married to Shulman since 2012 and the couple have two sons: Jonathan, six, and Jack, three.

In an October interview with Sirius XM’s Jess Cagle, Ann talked about being “more discerning” when it came to choosing roles, saying, “I’d have to say ‘the kids’ was the biggest change.”

‘[Kids] it kind of re-prioritized everything,” she told Cagle. “So it actually made me a little pickier because something really has to be that great to spend time away from them because they’re so precious to me.”

Calling his sons “the most sacred part of [her] life in general,” Anne continued, adding, “When I accept something, it puts more pressure on me to make the time away from them worth it.”

The love of her life: In a 2014 interview with Harper's Bazaar UK, the Les Miserables star said of Shulman:

The love of her life: In a 2014 interview with Harper’s Bazaar UK, the Les Miserables star said of Shulman: “From the second I met him, I knew he was the love of my life.”

Learning to Trust: Hathaway was still recovering from a bad breakup when she met Adam, which made her anxious at first.

Learning to Trust: Hathaway was still recovering from a bad breakup when she met Adam, which made her anxious at first. “I took my confidence for a ridiculous ride with him,” she told Harper’s Bazaar UK. ‘It was scary’

Better and better: The Princess Diaries star gave her husband-to-be a chance, explaining their relationship 'just keeps getting better and better'

Better and better: The Princess Diaries star gave her husband-to-be a chance, explaining their relationship ‘just keeps getting better and better’

In an interview with Harper’s Bazaar UK in 2013, the Les Miserables star said of Schulman: “From the second I met him, I knew he was the love of my life. Besides, I knew I couldn’t have met him at a worse time.

Hathaway was still recovering from a bad breakup, which made her anxious at first.

“I took my trust for a ridiculous ride with him,” she said. ‘It was scary.’

The Princess Diaries star has given her husband-to-be a chance, explaining that their relationship is “getting better and better”.

“He goes into a room,” burst out Anne, “and I light a fire. I can not help.

Lighting her up:

Lighting her up: “He walks into a room,” Ann gushed to Harper’s Bazaar UK, “and I light up. I can not help’; seen in 2011

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